| YEAR | DATE | EVENT | HEAD OF STATE |
| 722 | Bishopland | Bishop Bonifatius | |
| 754 | Bishop Lullus | ||
| 781 | Arcibishopland | Arcibishop Lullus | |
| 787 | Arcibishop Riculf | ||
| 813 | Arcibishop Haistulf | ||
| 826 | Arcibishop Otgar | ||
| 847 | Arcibishop Hrabanus Maurus | ||
| 856 | Arcibishop Charles of Aquitaine | ||
| 863 | Arcibishop Ludbert | ||
| 889 | Arcibishop Sunderold | ||
| 891 | Arcibishop Hatto I | ||
| 913 | Arcibishop Heriger | ||
| 927 | Arcibishop Hildebert | ||
| 937 | Arcibishop Friedrich | ||
| 954 | Arcibishop Wilhelm | ||
| 968 | Arcibishop Hatto II | ||
| 970 | Arcibishop Rudbrecht | ||
| 975 | Arcibishop Wilgis | ||
| 1011 | arcibishop Erchenbald | ||
| 1021 | arcibishop Aribo dinasty Aribonen | ||
| 1031 | arcibishop Bardo of Wettin | ||
| 1051 | arcibishop Leutpold of Babenberger | ||
| 1060 | arcibishop Sigfried I | ||
| 1084 | arcibishop Wezilo | ||
| 1089 | arcibishop Rudhart of Stein | ||
| 1109 | vacant | ||
| 1111 | arcibishop Adalbert I of Saar | ||
| 1137 | arcibishop Adalbert II of Saar | ||
| 1141 | arcibishop Markolf | ||
| 1142 | arcibishop Heinrich I | ||
| 1153 | arcibishop Arnold | ||
| 1161 | arcibishop Konrad I von Wittelsbach (I) | ||
| 1165 | arcibishop Christian I | ||
| 1183 | arcibishop Konrad I von Wittelsbach (II) | ||
| 1200 | arcibishop Sigfried II von Eppenstein | ||
| 1230 | arcibishop Sigfried III von Eppenstein | ||
| 1249 | arcibishop Christian III von Weissenau | ||
| 1251 | arcibishop Gerhard I von Daun-Kirberg | ||
| 1260 | arcibishop Werner II of Eppenstein | ||
| 1272 | 6° Electoral Principality | arcibishop Werner II of Eppenstein | |
| 1284 | vacant | ||
| 1286 | p.e. and arcibishop Gerhard II von Eppenstein | ||
| 1305 | p.e. and arcibishop Peter of Aspelt | ||
| 1321 | p.e. and arcibishop Matthias von Buchek | ||
| 1328 | p.e. and arcibishop Heinrich III von Virneberg | ||
| 1346 | p.e. and arcibishop Gerlack von Nassau | ||
| 1371 | p.e. and arcibishop Johann I von Luxemburg-Ligny | ||
| 1374 | p.e. and arcibishop Ludwig von Meissen | ||
| 1379 | p.e. and arcibishop Adolf I von Nassau | ||
| 1390 | p.e. and arcibishop Konrad II von Weinsberg | ||
| 1396 | p.e. and arcibishop Johann II von Nassau | ||
| 1419 | p.e. and arcibishop Konrad III Wild- und Rheinsgraf zum Stein | ||
| 1434 | p.e. and arcibishop Dietrich I | ||
| 1460 | p.e. and arcibishop Dieter von Isenburg (I) | ||
| 1461 | p.e. and arcibishop Adolf III von Nassau | ||
| 1476 | p.e. and arcibishop Dieter von Isenburg (II) | ||
| 1482 | p.e. and arcibishop Albert II of Saxe | ||
| 1484 | p.e. and arcibishop Bertold von Henneberg-Romhild | ||
| 1504 | p.e. and arcibishop Jakob von Liebenstein | ||
| 1508 | p.e. and arcibishop Uriel von Gemmingen | ||
| 1514 | p.e. and arcibishop Albert III von Brandenburg | ||
| 1545 | p.e. and arcibishop Sebastian von Heustenstamm | ||
| 1555 | p.e. and arcibishop Daniel Brendel von Homburg | ||
| 1582 | p.e. and arcibishop Wolfgang von Dalberg | ||
| 1601 | p.e. and arcibishop Johann Adam von Bicken | ||
| 1604 | p.e. and arcibishop Johann Schweikhard von Kronberg | ||
| 1626 | p.e. and arcibishop Georg Friedrich von Greiffenklau | ||
| 1629 | p.e. and arcibishop Anselm Casimir Wambold von Untadt | ||
| 1647 | p.e. and arcibishop Johann Philipp von Schönborn | ||
| 1673 | p.e. and arcibishop Lothar Friedrich von Metternich | ||
| 1675 | p.e. and arcibishop Damian Hartrad von Der Leyen | ||
| 1679 | p.e. and arcibishop Karl Heinrich von Metternich | ||
| 1679 | p.e. and arcibishop Anselm Franz von Ingelheim | ||
| 1695 | 30 march | p.e. and arcibishop Lothar Franz von Schönborn | |
| 1729 | 7 april | p.e. and arcibishop Franz Ludwig von Pfalzgraf-Neuburg | |
| 1732 | 9 june | p.e. and arcibishop Philipp Karl von Eltz | |
| 1743 | 22 april | p.e. and arcibishop Johann Friedrich Karl von Ostein | |
| 1763 | 5 july | p.e. and arcibishop Emmerich Josef von Briedbach | |
| 1774 | 18 july | p.e. and arcibishop Friedrich Karl Josef von Erthal | |
| 1802 | 4 july | p.e. and arcibishop Karl Theodor von Dalberg | |
| 1806 | 25 july | Principality of Francoforte | prince arcibishop Karl Theodor von Dalberg |
| 1810 | 16 february | Grandduchy | greatduke Carlo Antonio Teodoro Maria of Worms bishop of Regensburg |
| 1814 | Union to Landgraft of Hesse-Darmstadt | ||
| 1918 | 9 november | Union to Pfalz State |