| YEAR | DATE | EVENT | GOVERNOR |
| 1532 | Part of Spanish Viceroyalty of Peru | ||
| 1691 | 20 january | Mateo de la Mata Ponce de León | |
| 1703 | 28 august | Francisco López Dicastillo | |
| 1707 | may | Juan de Sosaya | |
| 1715 | 28 july | Santaigo Larraín | |
| 1717 | 27 may | Part of Spanish Viceroyalty of New Granada | |
| 1728 | 20 september | Dionisio de Alcedo y Herrera | |
| 1736 | 28 december | José de Araujo y Río | |
| 1745 | 12 march | Fernando Félix Sánchez de Orellana | |
| 1753 | 22 september | Juan Pío de Montúfar | |
| 1766 | september | Juan Antonio de Zelaya y Vergara | |
| 1767 | 17 july | José Diguja Villagómez | |
| 1778 | 23 november | José Garíca de León y Pizarro | |
| 1784 | Juan Jose de Villalengua y Marfil | ||
| 1790 | 29 april | Juan Antonio Mon y Valarde Pardo y Cienfuegos | |
| 1791 | 29 april | Luis Antonio Muñoz de Guzmán | |
| 1798 | 2 february | Luis Francisco Héctor de Carondelet de Novelles, barón de Carondelet | |
| 1808 | 1 august | Manuel Ruíz y Urriez de Castilla y Cavero, marqués de Ruíz de Castilla | |
| 1812 | 7 november | Toribio Montes | |
| 1817 | 26 july | Juan Ramírez de Orosco |